Phase Diagrams for Deformable Toroidal and Spherical Surfaces with Intrinsic Orientational Order

A theoretical study of toroidal membranes with various degrees of intrinsic orientational order is presented at mean-field level. The study uses a simple Ginzburg-Landau style free energy functional, which gives rise to a rich variety of physics and reveals some unusual ordered states. The system is found to exhibit many different phases with continuous and first order phase transitions, and phenomena including spontaneous symmetry breaking, ground states with nodes and the formation of vortex-antivortex quartets. Transitions between toroidal phases with different configurations of the order parameter and different aspect ratios are plotted as functions of the thermodynamic parameters. Regions of the phase diagrams in which spherical vesicles form are also shown.Comment: 40, revtex (with epsf), M/C.TH.94/2

Transforming from time to frequency without artefacts

I review a simple method, recently introduced to convert rheological compliance measurements into frequency-dependent moduli. New experimental data are presented, and the scientific implications of various data conversion methods discussed

Factorised steady states for multi-species mass transfer models

A general class of mass transport models with Q species of conserved mass is considered. The models are defined on a lattice with parallel discrete time update rules. For one-dimensional, totally asymmetric dynamics we derive necessary and sufficient conditions on the mass transfer dynamics under which the steady state factorises. We generalise the model to mass transfer on arbitrary lattices and present sufficient conditions for factorisation. In both cases, explicit results for random sequential update and continuous time limits are given.Comment: 11 page

Product Measure Steady States of Generalized Zero Range Processes

We establish necessary and sufficient conditions for the existence of factorizable steady states of the Generalized Zero Range Process. This process allows transitions from a site $i$ to a site $i+q$ involving multiple particles with rates depending on the content of the site $i$, the direction $q$ of movement, and the number of particles moving. We also show the sufficiency of a similar condition for the continuous time Mass Transport Process, where the mass at each site and the amount transferred in each transition are continuous variables; we conjecture that this is also a necessary condition.Comment: 9 pages, LaTeX with IOP style files. v2 has minor corrections; v3 has been rewritten for greater clarit

Soft core fluid in a quenched matrix of soft core particles: A mobile mixture in a model gel

We present a density-functional study of a binary phase-separating mixture of soft core particles immersed in a random matrix of quenched soft core particles of larger size. This is a model for a binary polymer mixture immersed in a crosslinked rigid polymer network. Using the replica `trick' for quenched-annealed mixtures we derive an explicit density functional theory that treats the quenched species on the level of its one-body density distribution. The relation to a set of effective external potentials acting on the annealed components is discussed. We relate matrix-induced condensation in bulk to the behaviour of the mixture around a single large particle. The interfacial properties of the binary mixture at a surface of the quenched matrix display a rich interplay between capillary condensation inside the bulk matrix and wetting phenomena at the matrix surface.Comment: 20 pages, 5 figures. Accepted for Phys. Rev.

Perturbative polydispersity: Phase equilibria of near-monodisperse systems

The conditions of multi-phase equilibrium are solved for generic polydisperse systems. The case of multiple polydispersity is treated, where several properties (e.g. size, charge, shape) simultaneously vary from one particle to another. By developing a perturbative expansion in the width of the distribution of constituent species, it is possible to calculate the effects of polydispersity alone, avoiding difficulties associated with the underlying many-body problem. Explicit formulae are derived in detail, for the partitioning of species at coexistence and for the shift of phase boundaries due to polydispersity. `Convective fractionation' is quantified, whereby one property (e.g. charge) is partitioned between phases due to a driving force on another. To demonstrate the ease of use and versatility of the formulae, they are applied to models of a chemically-polydisperse polymer blend, and of fluid-fluid coexistence in polydisperse colloid-polymer mixtures. In each case, the regime of coexistence is shown to be enlarged by polydispersity.Comment: 22 pages, 3 figure

Boundary layer integral matrix procedure code modifications and verifications

A summary of modifications to Aerotherm's Boundary Layer Integral Matrix Procedure (BLIMP) code is presented. These modifications represent a preliminary effort to make BLIMP compatible with other JANNAF codes and to adjust the code for specific application to rocket nozzle flows. Results of the initial verification of the code for prediction of rocket nozzle type flows are discussed. For those cases in which measured free stream flow conditions were used as input to the code, the boundary layer predictions and measurements are in excellent agreement. In two cases, with free stream flow conditions calculated by another JANNAF code (TDK) for use as input to BLIMP, the predictions and the data were in fair agreement for one case and in poor agreement for the other case. The poor agreement is believed to result from failure of the turbulent model in BLIMP to account for laminarization of a turbulent flow. Recommendations for further code modifications and improvements are also presented